Architects memo no.
44: April 1985
does your paint breathe? yes - quite deeply
when it gets excited!
Buzz words come and buzz words go, but breathability of paints
is one that has hung on for quite a while. It is in danger however of
being ousted by a new word from Europe, namely microporosity.
As both words relate to the same phenomenon, and because there seems
to be some confusion surrounding this area, we have decided to make
it a subject of a memo.
Breathability in essence has come to mean the ability of a
film to transmit a gaseous material at a far greater rate than the same
material in liquid form. Theoretically this applies to any liquid, but
in practice it means water; and a paint is said to have the ability
to breathe when it will keep rain off a substrate, but will allow that
substrate to dry out through the paint without damaging the film.
Permeability is measured by a unit weight of transmitted material
(e.g. water vapour) passing through a unit area for a unit time, through
a specific thickness of film. It is obvious, but worth underlining,
that the breathability of any film decreases the thicker the film is
The actual mechanics of breathing is that of a molecule of
water wriggling its way through and between adjacent molecules in the
film. The size and the shape of these molecular gaps affects the rate
at which the water molecule can penetrate. Polyvinyl acetates and acrylics
are known as polar polymers because of their characteristic molecular
arrangement, and generally allow water vapour to pass through readily.
On the other hand non-polar polymers such as chlorinated rubber
and polystyrene greatly restrict the passage of water and vapour.
The introduction of pigments and fillers into films can also influence
the water vapour transmission by providing extra channels for water
to get through if the pigment or filler is of an irregular-shaped porous
nature, or by increasing barriers if it is of a platey, reinforcing
nature. Levels of these materials also effect the transmission particularly
if they are at such a high level that there is insufficient polymer
present to bind everything into a continuous film. In such circumstances
rather large holes can be left in the film.
To get some indication of the size of a hole needed to allow
a molecule of water to pass through it, one droplet of water contains
about thirty billion, trillion molecules; there are very few materials
that can totally prevent one or two of these little fellows squeezing
In conclusion we can say that virtually every paint can breathe and
that the major differences are in the rate of breathing. This rate alters
with polymer type and with type and level of pigments. A flat PVA
will be one of the most water permeable paints available whilst a gloss
chlorinated rubber the least. A system breathes sufficiently if, for
any specific job, any moisture in the substrate can escape (to prevent
the build up of damage patches) without causing blistering or flaking
of the paint. This becomes a numbers game and a successful system can
fail when another coat of the same material is added!
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